Round 23 Matches
| 02/08/2019 at 21:00 | Real Valladolid - Villarreal | 0 - 0 [FT] |
| 02/09/2019 at 13:00 | Getafe - Celta Vigo | 3 - 1 [FT] |
| 02/09/2019 at 16:15 | Atletico Madrid - Real Madrid | 1 - 3 [FT] |
| 02/09/2019 at 18:30 | Espanyol - Rayo Vallecano | 2 - 1 [FT] |
| 02/09/2019 at 20:45 | Girona - Huesca | 0 - 2 [FT] |
| 02/10/2019 at 12:00 | Leganes - Real Betis | 3 - 0 [FT] |
| 02/10/2019 at 16:15 | Valencia - Real Sociedad | 0 - 0 [FT] |
| 02/10/2019 at 18:30 | Sevilla - Eibar | 2 - 2 [FT] |
| 02/10/2019 at 20:45 | Athletic Bilbao - Barcelona | 0 - 0 [FT] |
| 02/11/2019 at 21:00 | Alaves - Levante | 2 - 0 [FT] |
Valencia - Barcelona 1 - 1
| G | Neto | Marc-Andre ter Stegen | G |
| D | Cristiano Piccini | Jordi Alba | D |
| D | Gabriel | Nelson Semedo | D |
| D | Jose Gaya | Gerard Pique | D |
| D | Ezequiel Garay  | Thomas Vermaelen | D |
| M | Goncalo Guedes  | Arthur | M |
| M | Daniel Parejo  | Sergio Busquets | M |
| M | Geoffrey Kondogbia | Coutinho | M |
| M | Carlos Soler | Ivan Rakitic | M |
| S | Kevin Gameiro | Lionel Messi | S |
| S | Michy Batshuayi |  Luis Suarez | S |
| M | Francis Coquelin  | Rafinha | M |
| M | Denis Cheryshev | Ousmane Dembele | M |
| S | Rodrigo Moreno |